Iron Catalyzed Oxidation Reaction

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Iron II Catalyzed Aerobic Biomimetic Oxidation of Amines

The iron alyzed biomimetic oxidation of PMPprotected benzylamine 3 a PMPpmethoxyphenyl as model substrate was run in anisole as solvent using 10 mol of iron alyst IIa, TMANO, and hybrid alyst I under air.

Frontiers IronCatalyzed Oxidation of 1Phenylethanol and

Aerobic alcohol oxidation and oxygen atom transfer reactions alyzed by a nonheme iron II keto acid complex. Chem. Sci . 7, 53225331. doi: 10.1039/C6SC01476C

An iron alyzed regioselective oxidation of terminal

Fe BF4 26H2O with pyridine2,6dicarboxylic acid and PhIO can efficiently alyze the regioselective oxidation of terminal alkene derivatives to aldehydes under mild and benign reaction conditions.

Iron II Catalyzed Aerobic Biomimetic Oxidation of Amines

After the completion of that study, we envisioned that a similar iron alyzed biomimetic oxidation of amine substrates by molecular oxygen might be feasible, in particular since the corresponding ruthenium alyzed aerobic oxidation of amines had previously been realized with the same ETMs. 5b Surprisingly, attempts to use these two ETMs

Iron II Catalyzed Aerobic Biomimetic Oxidation of N

Metal alyzed dehydrogenative reactions of 1,2,3,4tetrahydroquinoline have previously been reported. 18 Herein, we report an iron alyzed biomimetic aerobic oxidation of various Nheterocycles using the bifunctional hybrid alyst IId as an efficient ETM.

Iron II Catalyzed Aerobic Biomimetic Oxidation of NHeterocycles

We envisaged that the reaction conditions for the iron alyzed biomimetic aerobic oxidation of amines could also be used for the oxidation of Nheterocycles Scheme 2C . Metal alyzed dehydrogenative reactions of 1,2,3,4tetrahydroquinoline have previously been reported. 18 Herein, we report an iron

Iron II Catalyzed Biomimetic Aerobic Oxidation of Alcohols

Our initial attempts began by investigating various 1,4benzoquinones as stoichiometric oxidants in the iron alyzed oxidation of 1phenylethanol 1 a using I as alyst. Of the quinones tested, 2,6dimethoxy1,4benzoquinone DMBQ was found to be the best, giving acetophenone 2 a in a yield of 9 after 60 min see Table S1 in the

Selective oxidation of glycerol alyzed by iron complexes

The first report on iron alyzed glycerol oxidation by hydrogen peroxide dates back to 1899 other studies on alcohol and/or glycerol oxidation in the presence of iron salts followed in the last century and appeared also recently . A common feature of the ironpromoted glycerol oxidation so far reported was the formation of mixtures of

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